Hastelloy Pipe
Hastelloy is a family of nickel-based superalloys developed by Haynes International, engineered for extreme corrosion resistance in both oxidizing and reducing environments. Hastelloy pipes are specified when stainless steel, duplex, and even Inconel grades cannot withstand the corrosive media.
The two most common Hastelloy pipe grades are C-276 (the industry workhorse) and C-22 (improved resistance to oxidizing media).
Hastelloy Grades Compared
| Property | C-276 | C-22 | B-3 |
|---|---|---|---|
| UNS | N10276 | N06022 | N10675 |
| Ni (%) | 57 (bal.) | 56 (bal.) | 65 (bal.) |
| Cr (%) | 14.5-16.5 | 20-22.5 | 1-3 |
| Mo (%) | 15-17 | 12.5-14.5 | 27-32 |
| W (%) | 3-4.5 | 2.5-3.5 | - |
| Fe (%) | 4-7 | 2-6 | 1-3 |
| Yield (min, annealed) | 283 MPa (41 ksi) | 310 MPa (45 ksi) | 283 MPa (41 ksi) |
| Tensile (min, annealed) | 690 MPa (100 ksi) | 690 MPa (100 ksi) | 690 MPa (100 ksi) |
| ASTM pipe (seamless) | B622 | B622 | B622 |
| ASTM pipe (welded) | B619 | B619 | B619 |
| Primary strength | Universal corrosion resistance | Oxidizing + reducing media | HCl, H2SO4 (reducing) |
Hastelloy C-276: The Workhorse
C-276 is often called the “universal alloy” because it resists an unusually broad range of corrosive chemicals:
- Sulfuric acid (all concentrations, including hot dilute)
- Hydrochloric acid (up to 50°C in all concentrations)
- Phosphoric acid (with impurities)
- Wet chlorine gas and hypochlorite solutions
- Ferric and cupric chloride solutions (highly oxidizing)
- Acetic, formic, and other organic acids
This versatility makes C-276 the default choice when the process involves mixed or variable chemical compositions.
Hastelloy C-22: Enhanced Oxidizing Resistance
C-22 improves on C-276 in oxidizing environments due to its higher chromium content (20-22.5% vs. 14.5-16.5%). It resists:
- Oxidizing acids with chlorides better than C-276
- Mixed acid environments (nitric + HCl, sulfuric + HCl)
- Pharmaceutical process streams with aggressive cleaning chemicals
Hastelloy B-3: Reducing Acid Specialist
B-3 contains 27-32% molybdenum and minimal chromium, making it the best choice for reducing acids without oxidizing contaminants:
- Hydrochloric acid at all concentrations up to boiling
- Sulfuric acid in reducing (deaerated) conditions
- Acetic acid and other organic acids
Applications
- Chemical processing reactors and piping
- Pharmaceutical manufacturing
- Flue-gas desulfurization (FGD) systems in power plants
- Waste treatment (incineration off-gas scrubbing)
- Pulp and paper bleaching
- Pesticide and herbicide production
Cost and Procurement
| Material | Approximate Cost Multiple (vs. CS) |
|---|---|
| Carbon steel (A106 Gr. B) | 1x |
| 316L stainless | 3-4x |
| Inconel 625 | 10-15x |
| Hastelloy C-276 | 15-25x |
| Hastelloy C-22 | 18-28x |
Lead times for seamless Hastelloy pipe typically range from 20-30 weeks. Early procurement planning is essential. For large diameters where seamless is unavailable, welded pipe per ASTM B619 (with solution annealing) is specified.
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