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What Is ASTM A182?

Grades at a Glance

ASTM A182 encompasses dozens of grades across three material families. The table below covers the most frequently specified grades.

GradeAlloy TypeWrought Equiv.Cast Equiv.Max TempPrimary Use
F1C-1/2MoA335 P1A217 WC1455°CModerate high-temp
F111-1/4Cr-1/2MoA335 P11A217 WC6565°CRefinery, power
F222-1/4Cr-1MoA335 P22A217 WC9595°CHydroprocessing
F55Cr-1/2MoA335 P5A217 C5650°CHigh-sulfur crude
F99Cr-1MoA335 P9A217 C12650°CPower, refinery
F919Cr-1Mo-VA335 P91A217 C12A650°CSupercritical steam
F30418Cr-8NiA312 TP304A351 CF8538°CCorrosive service
F31616Cr-10Ni-2MoA312 TP316A351 CF8M538°CChloride/marine
F304L18Cr-8Ni (low C)A312 TP304LA351 CF3425°CWelded assemblies
F316L16Cr-10Ni-2Mo (low C)A312 TP316LA351 CF3M425°CWelded, corrosive
F32118Cr-10Ni-TiA312 TP321-538°CHigh-temp stainless
F5122Cr-5Ni-3Mo (Duplex)A790 S31803A995 4A315°COffshore, sour

Alloy Steel Grades (F11, F22, F5, F9, F91)

These chrome-moly grades provide creep strength and oxidation resistance at temperatures above the 425°C limit of carbon steel. They match ASTM A335 alloy pipes and ASTM A217 cast valve bodies. Heat treatment is mandatory: normalize and temper, or quench and temper. A182 F11 is the most common grade for refinery high-temperature service.

Stainless Steel Grades (F304, F316, F321)

Austenitic stainless grades provide corrosion resistance from cryogenic (-254°C) to 538°C. F304 vs F316 is the most common selection decision: F316’s molybdenum content provides superior pitting resistance in chloride environments. Solution annealing is required for all austenitic grades.

Mechanical Properties (Selected Grades)

GradeTensile (min)Yield (min)Elongation (min)Hardness (max)
F11 Cl.2485 MPa275 MPa20%197 HBW
F22 Cl.3515 MPa310 MPa20%197 HBW
F304515 MPa205 MPa30%183 HBW
F316515 MPa205 MPa30%183 HBW
F51620 MPa450 MPa25%293 HBW

Testing and Certification

ASTM A182 requires chemical analysis, tensile testing, hardness testing, and heat treatment per grade. Mill test certificates document all results. Supplementary requirements include impact testing, ultrasonic and magnetic particle examination, hydrostatic testing, and intergranular corrosion testing (for austenitic grades per ASTM A262). The forging process produces a refined grain structure superior to castings for fatigue and impact resistance.

Read the full guide to valve materials

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